Can this material replace a finished bleach activator?
No. It is a synthesis intermediate for producing phenolsulfonate ester derivatives, rather than a direct replacement for the finished activator.

| Item | Data |
|---|---|
| CAS number | 10580-19-5 |
| Chemical name | Sodium 4-Hydroxybenzenesulfonate Dihydrate |
| Common synonym | Sodium p-Phenolsulfonate Dihydrate |
| Molecular formula | C6H5NaO4S·2H2O |
| Molecular weight | 232.19 g/mol |
| Physical form | Crystalline powder or crystals |
| Appearance | White to off-white |
| Hydration state | Dihydrate |
| Water of crystallization, theoretical | Approximately 15.52 wt% |
The para-substituted structure combines a phenolic hydroxyl group with a sodium sulfonate group on the same aromatic ring. The hydroxyl group provides a reaction site for ester and ether formation. This combination makes the material useful as a starting intermediate for sulfonated organic derivatives, including compounds used further downstream in detergent ingredient manufacture.
The crystalline dihydrate is a solid feedstock for subsequent processing into solutions, slurries or dehydrated material. Its suitability for a particular conversion depends on the reaction system. In ester manufacture, water removal is especially relevant because moisture can consume the acylating reagent through hydrolysis and reduce conversion to the target ester.
Sodium p-phenolsulfonate is a starting intermediate for acyloxybenzenesulfonates, a family that includes detergent bleach activators. These derivatives are prepared by reacting the phenolic functionality with an appropriate acylating component. The dihydrate serves as an upstream feedstock, with dehydration incorporated into moisture-sensitive production routes. The resulting ester is the downstream detergent ingredient; CAS 10580-19-5 is the starting raw material.
Phenolsulfonate ester routes include reactions with carboxylic acid chlorides and acid anhydrides. The acyl component determines the structure of the resulting derivative. This gives the intermediate a defined role in the synthesis of different acyloxybenzenesulfonates, rather than a direct bleaching role in a finished detergent formulation.
The phenolic hydroxyl group can also undergo O-alkylation to form ether-linked aromatic sulfonates. One demonstrated conversion produces sodium 4-(2-methyl-2-propenoxy)benzenesulfonate from the dihydrate. This route adds an unsaturated side chain while retaining the aromatic sulfonate structure. Such derivatives provide starting points for further chemical modification in specialty synthesis.
The dihydrate contains two waters of crystallization. Water-sensitive acylation uses dehydrated phenolsulfonate feed, because retained water can hydrolyse acid chlorides or anhydrides during the reaction. A low residual-water requirement at the acylation stage therefore involves a separate drying operation when the incoming material is the dihydrate.
Drying also affects the physical condition and reactivity of the phenolsulfonate feed. Excessive thermal exposure can promote side reactions and affect subsequent ester conversion and product colour. Drying temperature and residence time are process-specific.
Store in a tightly closed container in a cool, dry, well-ventilated place, protected from direct light. Keep separate from strong oxidizing agents. Control dust during transfer and charging, and follow the product SDS for workplace protection and handling precautions.
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No. It is a synthesis intermediate for producing phenolsulfonate ester derivatives, rather than a direct replacement for the finished activator.
The dihydrate requires suitable dehydration before a moisture-sensitive acylation stage. The residual-water limit belongs to the specific production process.
No. This product enquiry is intended for commercial manufacturing and industrial raw material procurement.
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Request a commercial quotation for sodium 4-hydroxybenzenesulfonate dihydrate, CAS 10580-19-5. Include the quantity and destination, together with any required specification, COA, TDS or SDS.